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Reactivity of Niobium(V) ComplexTowards Hydroxamate LigandsBy Dr Mala Sharma, Dr Kumari Bandna
Abstract: A niobium(V) complex with the composition [NbCl(OC₆H₄CH(CH₃)₂-2)₄] was synthesized by reacting niobium pentachloride with four equivalents of 2-isopropylphenol in carbon tetrachloride as a solvent, yielding the product in good quantity. The complex was characterized using elemental analysis, molar conductance measurements, IR spectroscopy, ¹H and ¹³C NMR spectroscopy, and mass spectrometry. Spectroscopic results indicate that the complex exists in a dimeric form, with bridging occurring through isopropylphenoxo ligands. X-ray diffraction analysis …
Published in International Journal of Energetic Materials · Vol. 12, Issue 1, 2026 · pp. 1–6 Read article →