This study explores the potential of beryllium (Be) and transition metal (TM) complexes in hydrogen storage and production, focusing on the hybridization of atomic orbitals to form dihydrogen complexes within nanostructured materials. We analyze the binding energies and adsorption characteristics of H₂ molecules in Be-dihydrogen complexes and compare them with TM-dihydrogen complexes. The findings indicate that Be can effectively bind H₂ at room temperature, making it a promising candidate for hydrogen storage applications. Furthermore, the synthesis of RuBe nanosheets demonstrates enhanced catalytic activity for alkaline hydrogen evolution, providing insights into efficient hydrogen production methods. Additionally, we introduce a speckle suppressor device employing nanoberyllium to improve X-ray imaging, showcasing the multifunctionality of beryllium in advanced material applications. This work offers valuable perspectives for future research into hydrogen storage and production technologies, emphasizing the significance of nanostructured materials in energy applications.

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1. Lee H, Huang B, Duan W, Ihm J. Beryllium-dihydrogen complexes on nanostructures. Appl Phys Lett. 2010;96:143120. doi:10.1063/1.3387754.
2. Xu J, Wang S, Yang C, Li T, Liu Q, Kong X. Free-standing two-dimensional ruthenium-beryllium nanosheets for alkaline hydrogen evolution. Chem Eng J. 2021;421:129741. doi:10.1016/j.cej.2021.129741
3. Goikhman A, Lyatun I, Ershov P, Snigireva I, Wojda P, Gorlevsky V, et al. Highly porous nanoberyllium for X-ray beam speckle suppression. J Synchrotron Radiat. 2015;22(3):796–800. doi:10.1107/S1600577515003628.
4. Walsh KA. Beryllium Chemistry and Processing. U.S.A: ASM international; 2009.
5. Saeed M, Marwani HM, Shahzad U, Asiri AM, Hussain I, Rahman MM. Utilizing nanostructured materials for hydrogen generation, storage, and diverse applications. Chem Asian J. 2024;19(16):e202300593. doi:10.1002/asia.202300593.
6. Scott M, Powells G. Sensing hydrogen transitions in homes through social practices: Cooking, heating, and the decomposition of demand. Int J Hydrogen Energy. 2020;45(7):3870–3882. doi:10.1016/j.ijhydene.2019.12.025.
7. Habib MA, Abdulrahman GA, Alquaity AB, Qasem NA. Hydrogen combustion, production, and applications: A review. Alex Eng J. 2024;100:182–207. doi:10.1016/j.aej.2024.05.030.
8. Perivoliotis DK, Ekspong J, Zhao X, Hu G, Wågberg T, Gracia-Espino E. Recent progress on defect-rich electrocatalysts for hydrogen and oxygen evolution reactions. Nano Today. 2023;50:101883. doi:10.1016/j.nantod.2023.101883.

This study explores the potential of beryllium (Be) and transition metal (TM) complexes in hydrogen storage and production, focusing on the hybridization of atomic orbitals to form dihydrogen complexes within nanostructured materials. We analyze the binding energies and adsorption characteristics of H₂ molecules in Be-dihydrogen complexes and compare them with TM-dihydrogen complexes. The findings indicate that Be can effectively bind H₂ at room temperature, making it a promising candidate for hydrogen storage applications. Furthermore, the synthesis of RuBe nanosheets demonstrates enhanced catalytic activity for alkaline hydrogen evolution, providing insights into efficient hydrogen production methods. Additionally, we introduce a speckle suppressor device employing nanoberyllium to improve X-ray imaging, showcasing the multifunctionality of beryllium in advanced material applications. This work offers valuable perspectives for future research into hydrogen storage and production technologies, emphasizing the significance of nanostructured materials in energy applications.

🔒 This is a subscription article

Full text is available to subscribers and institutional members. Please choose an option below to access it.

1. Lee H, Huang B, Duan W, Ihm J. Beryllium-dihydrogen complexes on nanostructures. Appl Phys Lett. 2010;96:143120. doi:10.1063/1.3387754.
2. Xu J, Wang S, Yang C, Li T, Liu Q, Kong X. Free-standing two-dimensional ruthenium-beryllium nanosheets for alkaline hydrogen evolution. Chem Eng J. 2021;421:129741. doi:10.1016/j.cej.2021.129741
3. Goikhman A, Lyatun I, Ershov P, Snigireva I, Wojda P, Gorlevsky V, et al. Highly porous nanoberyllium for X-ray beam speckle suppression. J Synchrotron Radiat. 2015;22(3):796–800. doi:10.1107/S1600577515003628.
4. Walsh KA. Beryllium Chemistry and Processing. U.S.A: ASM international; 2009.
5. Saeed M, Marwani HM, Shahzad U, Asiri AM, Hussain I, Rahman MM. Utilizing nanostructured materials for hydrogen generation, storage, and diverse applications. Chem Asian J. 2024;19(16):e202300593. doi:10.1002/asia.202300593.
6. Scott M, Powells G. Sensing hydrogen transitions in homes through social practices: Cooking, heating, and the decomposition of demand. Int J Hydrogen Energy. 2020;45(7):3870–3882. doi:10.1016/j.ijhydene.2019.12.025.
7. Habib MA, Abdulrahman GA, Alquaity AB, Qasem NA. Hydrogen combustion, production, and applications: A review. Alex Eng J. 2024;100:182–207. doi:10.1016/j.aej.2024.05.030.
8. Perivoliotis DK, Ekspong J, Zhao X, Hu G, Wågberg T, Gracia-Espino E. Recent progress on defect-rich electrocatalysts for hydrogen and oxygen evolution reactions. Nano Today. 2023;50:101883. doi:10.1016/j.nantod.2023.101883.