A Review on Bio-oil Production from Agricultural Waste Based on Various Processes, Bio-oil Yield and Energy Recovery

Volume: 11 | Issue: 1 | Year 2025 | Subscription
International Journal of Nanomaterials and Nanostructures
Received Date: 02/04/2025
Acceptance Date: 02/21/2025
Published On: 2025-04-07
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By: Rajat Chakraborty, Sonali Samanta, and Asit Kumar Saha

Abstract

Agricultural wastes generated through cultivation of crops, vegetables, fruits, and poultry can pollute the environment and affect the health of both humans and animals. Traditionally, most agricultural wastes are either burned or disposed of in landfills which cause acute environmental pollution. These easily accessible and underutilized agro-wastes remain a potential resource for biofuel production. This review analyses several thermochemical and biochemical methods encompassing pyrolysis, gasification, and hydrothermal carbonization (HTC) and fermentation to convert agricultural wastes including crop stalks, husks, straw, and bagasse into biofuel. The highly accepted method is pyrolysis which results in bio-oil; whereas, gasification produces syngas utilized for electric power production as well as conversion to liquid fuels. HTC at lower temperature and pressure produces hydrochar which can act as a solid fuel or be transformed into liquid biofuels. Apart from biofuels, biochar, which is a by-product of pyrolysis, HTL and gasification processes, is also useful in the enhancement of soils as well as for carbon storage. Based on the energy recovery, the processes are ranked as follows: Fermentation> Pyrolysis>HTL. Despite its potential, geographical diversity causes feedstock variability necessitating process optimization, technology advancement, economic feasibility toward sustainable implementation. Additionally, scalability and environmental concerns, including pollutant emissions, need to be addressed for large-scale commercial biofuel production.

Keywords: Agricultural Waste, Bio-oil, Production Process, Yield of Bio-oil, Energy Recovery.

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How to cite this article: Rajat Chakraborty, Sonali Samanta, and Asit Kumar Saha, A Review on Bio-oil Production from Agricultural Waste Based on Various Processes, Bio-oil Yield and Energy Recovery. International Journal of Nanomaterials and Nanostructures. 2025; 11(1): -p.

How to cite this URL: Rajat Chakraborty, Sonali Samanta, and Asit Kumar Saha, A Review on Bio-oil Production from Agricultural Waste Based on Various Processes, Bio-oil Yield and Energy Recovery. International Journal of Nanomaterials and Nanostructures. 2025; 11(1): -p. Available from:https://journalspub.com/publication/ijnn/article=16026

Refrences:

  1. Díaz-Padilla VT, Travar I, Acosta-Rubio Z, Parra-López E. Tourism Competitiveness versus Sustainability: Impact on the World Economic Forum Model Using the Rasch Methodology. Sustainability. 2023 Sep 14;15(18):13700.
  2. Sharma S, Soederberg S. Redesigning the business of development: The case of the World Economic Forum and global risk management. Review of International Political Economy. 2020 Jul 3;27(4):828-54.
  3. Riseh RS, Vazvani MG, Hassanisaadi M, Thakur VK. Agricultural wastes: A practical and potential source for the isolation and preparation of cellulose and application in agriculture and different industries. Industrial Crops and Products. 2024 Feb 1;208:117904.
  4. Channi AS, Bains HS, Grewal JS, Chidambranathan VS, Kumar R. Tool wear rate during electrical discharge machining for aluminium metal matrix composite prepared by squeeze casting: A prospect as a biomaterial. Journal of Electrochemical Science and Engineering. 2023 Feb 19;13(1):149-62.
  5. Agrizzi T, Oliveira MA, Faria EV, Santos KG, Xavier TP, Lira TS. Assessing coconut shell pyrolysis: Biomass characterization, activation energy estimation, and statistical analysis of operating conditions. Bioresource Technology Reports. 2024 Jun 1;26:101831.
  6. do Nascimento VR, dos Santos MB, Diehl L, Paniz JN, de Castilhos F, Bizzi CA. Microwave-assisted pyrolysis of pine wood waste: system development, biofuels production, and characterization. Journal of Analytical and Applied Pyrolysis. 2024 Oct 9:106799.
  7. Borges FC, Du Z, Xie Q, Trierweiler JO, Cheng Y, Wan Y, Liu Y, Zhu R, Lin X, Chen P, Ruan R. Fast microwave assisted pyrolysis of biomass using microwave absorbent. Bioresource technology. 2014 Mar 1;156:267-74.
  8. Kostas ET, Durán-Jiménez G, Shepherd BJ, Meredith W, Stevens LA, Williams OS, Lye GJ, Robinson JP. Microwave pyrolysis of olive pomace for bio-oil and bio-char production. Chemical Engineering Journal. 2020 May 1;387:123404.
  9. Ighalo JO, Rangabhashiyam S, Dulta K, Umeh CT, Iwuozor KO, Aniagor CO, Eshiemogie SO, Iwuchukwu FU, Igwegbe CA. Recent advances in hydrochar application for the adsorptive removal of wastewater pollutants. Chemical Engineering Research and Design. 2022 Aug 1;184:419-56.
  10. Enaime G, Baçaoui A, Yaacoubi A, Lübken M. Biochar for wastewater treatment—conversion technologies and applications. Applied Sciences. 2020 May 18;10(10):3492.
  11. Rombel A, Krasucka P, Oleszczuk P. Sustainable biochar-based soil fertilizers and amendments as a new trend in biochar research. Science of the Total Environment. 2022 Apr 10;816:151588.
  12. Zheng JL, Zhu YH, Zhu MQ, Kang K, Sun RC. A review of gasification of bio-oil for gas production. Sustainable Energy & Fuels. 2019;3(7):1600-22.
  13. Younas R, Hao S, Zhang L, Zhang S. Hydrothermal liquefaction of rice straw with NiO nanocatalyst for bio-oil production. Renewable Energy. 2017 Dec 1;113:532-45.
  14. Liu Z, Balasubramanian R. Upgrading of waste biomass by hydrothermal carbonization (HTC) and low temperature pyrolysis (LTP): A comparative evaluation. Applied Energy. 2014 Feb 1;114:857-64.
  15. Guddaraddi A, Singh A, Amrutha G, Saikanth DR, Kurmi R, Singh G, Chowdhury M, Singh BV. Sustainable biofuel production from agricultural residues an eco-friendly approach: a review. Int J Environ Clim Change. 2023;13(10):2905-14.
  16. Gheewala SH, Damen B, Shi X. Biofuels: economic, environmental and social benefits and costs for developing countries in Asia. Wiley Interdisciplinary Reviews: Climate Change. 2013 Nov;4(6):497-511.
  17. Mohanty A, Ajmera S, Chinnam S, Kumar V, Mishra RK, Acharya B. Pyrolysis of waste oils for biofuel production: An economic and life cycle assessment. Fuel Communications. 2024 Mar 1;18:100108.
  18. Patra BR, Nanda S, Dalai AK, Meda V. Slow pyrolysis of agro-food wastes and physicochemical characterization of biofuel products. Chemosphere. 2021 Dec 1;285:131431.
  19. Bridgwater AV. Review of fast pyrolysis of biomass and product upgrading. Biomass and bioenergy. 2012 Mar 1;38:68-94.
  20. Ge S, Yek PN, Cheng YW, Xia C, Mahari WA, Liew RK, Peng W, Yuan TQ, Tabatabaei M, Aghbashlo M, Sonne C. Progress in microwave pyrolysis conversion of agricultural waste to value-added biofuels: a batch to continuous approach. Renewable and Sustainable Energy Reviews. 2021 Jan 1;135:110148.
  21. Xue Z, Zhong Z, Zhang B, Xu C. Performance of catalytic fast pyrolysis using a γ-Al2O3 catalyst with compound modification of ZrO2 and CeO2. Catalysts. 2019 Oct 12;9(10):849.
  22. Czernik S. Catalytic pyrolysis of biomass. Advanced biofuels and bioproducts. 2012 Jun 7:119-27.
  23. Gollakota AR, Kawale HD, Kishore N, Gu S. Corrigendum to “a review on hydrothermal liquefaction of biomass”[Renew Sustain Energy Rev 81 (2018) 1378–1392]. Renewable and Sustainable Energy Reviews. 2018 Dec 1;98:515-7.
  24. Biller P, Ross AB. Production of biofuels via hydrothermal conversion. InHandbook of biofuels production 2016 Jan 1 (pp. 509-547). Woodhead Publishing.
  25. Devi GS, Vaishnavi S, Srinath S, Dutt B, Rajmohan KS. Energy recovery from biomass using gasification. InCurrent developments in biotechnology and bioengineering 2020 Jan 1 (pp. 363-382). Elsevier.
  26. Rastogi M, Shrivastava S. Recent advances in second generation bioethanol production: An insight to pretreatment, saccharification and fermentation processes. Renewable and Sustainable Energy Reviews. 2017 Dec 1;80:330-40.
  27. Muktham R, Bhargava SK, Bankupalli S, Ball AS. A review on 1st and 2nd generation bioethanol production-recent progress. Journal of Sustainable Bioenergy Systems. 2016 Jul 8;6(3):72-92.
  28. Nuraini N, binti Osman N, Astuti E. Bio-Oil Production Using Waste Biomass via Pyrolysis Process: Mini Review. Jurnal Bahan Alam Terbarukan. 2022 Jun 20;11(1):37-49.
  29. Mohamed OA. Production of bio-oil from agriculture waste. Biochem Anal Biochem. 2018;7(348):2161-1009.
  30. Paul AS, Panwar NL, Salvi BL, Jain S, Sharma D. Experimental investigation on the production of bio-oil from wheat straw. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. 2024 Dec 31;46(1):9777-92.
  31. Fardhyanti DS, Chafidz A, Triwibowo B, Prasetiawan H, Cahyani NN, Andriyani S. Improving the quality of bio-oil produced from rice husk pyrolysis by extraction of its phenolic compounds. Jurnal Bahan Alam Terbarukan. 2020 Dec 17;8(2):90-100.
  32. da Cunha Gonçalves G, Pereira NC, Veit MT. Production of bio-oil and activated carbon from sugarcane bagasse and molasses. Biomass and Bioenergy. 2016 Feb 1;85:178-86.
  33. Asadullah M, Ab Rasid NS, Kadir SA, Azdarpour A. Production and detailed characterization of bio-oil from fast pyrolysis of palm kernel shell. Biomass and Bioenergy. 2013 Dec 1;59:316-24.
  34. Shafie NH, Esa NM. The healing components of rice bran. Functional Foods: Wonder of the World. Evidence-Based Functional Foods in Health & Disease. 2017:341-68.
  35. Wakatuntu J, Olupot PW, Jjagwe J, Menya E, Okure M. Optimization of pyrolysis conditions for production of rice husk-based bio-oil as an energy carrier. Results in Engineering. 2023 Mar 1;17:100947.
  36. Kordi M, Farrokhi N, Pech-Canul MI, Ahmadikhah A. Rice husk at a glance: from agro-industrial to modern applications. Rice Science. 2024 Jan 1;31(1):14-32.
  37. Cai W, Liu R, He Y, Chai M, Cai J. Bio-oil production from fast pyrolysis of rice husk in a commercial-scale plant with a downdraft circulating fluidized bed reactor. Fuel processing technology. 2018 Mar 1;171:308-17.
  38. Alvarez J, Lopez G, Amutio M, Bilbao J, Olazar M. Bio-oil production from rice husk fast pyrolysis in a conical spouted bed reactor. Fuel. 2014 Jul 15;128:162-9.
  39. Li Z, Zhong Z, Zhang B, Wang W, Zhao H, Seufitelli GV, Resende FL. Microwave-assisted catalytic fast pyrolysis of rice husk over a hierarchical HZSM-5/MCM-41 catalyst prepared by organic base alkaline solutions. Science of The Total Environment. 2021 Jan 1;750:141215.
  40. Liu Y, Yuan XZ, Huang HJ, Wang XL, Wang H, Zeng GM. Thermochemical liquefaction of rice husk for bio-oil production in mixed solvent (ethanol–water). Fuel Processing Technology. 2013 Aug 1;112:93-9.
  41. Chavan S, Mitra D, Ray A. Harnessing rice husks: Bioethanol production for sustainable future. Current Research in Microbial Sciences. 2024 Oct 26:100298.
  42. Shi W, Li S, Jin H, Zhao Y, Yu W. The hydrothermal liquefaction of rice husk to bio-crude using metallic oxide catalysts. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects. 2013 Nov 17;35(22):2149-55.
  43. Unrean P, Fui BC, Rianawati E, Acda M. Comparative techno-economic assessment and environmental impacts of rice husk-to-fuel conversion technologies. Energy. 2018 May 15;151:581-93.
  44. Song Y, Maskey S, Lee YG, Lee DS, Nguyen DT, Bae HJ. Optimizing bioconversion processes of rice husk into value-added products: D-psicose, bioethanol, and lactic acid. Bioresource Technology. 2024 Mar 1;395:130363.
  45. Thinh NV, Thu HN, Thao NV, Vy NT. Rice straw management in Mekong Delta: a case study in Long An Province. InThe Mekong Delta Environmental Research Guidebook 2025 Jan 1 (pp. 283-301). Elsevier.
  46. Lazzari E, Schena T, Primaz CT, da Silva Maciel GP, Machado ME, Cardoso CA, Jacques RA, Caramão EB. Production and chromatographic characterization of bio-oil from the pyrolysis of mango seed waste. Industrial Crops and Products. 2016 May 1;83:529-36.
  47. Beneroso D, Monti T, Kostas ET, Robinson J. Microwave pyrolysis of biomass for bio-oil production: scalable processing concepts. Chemical Engineering Journal. 2017 May 15;316:481-98.
  48. Panwar NL, Paul AS. An overview of recent development in bio-oil upgrading and separation techniques. Environmental Engineering Research. 2021 Oct;26(5).
  49. Bridgewater AV. Biomass fast pyrolysis. Thermal science. 2004;8(2):21-50.