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621 articles
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Identification of the Most Stable Guanine Tautomer for Hydroxylation Reaction Mechanism Studies using DFT calculations
Abstract: Abstract: Identifying the most stable tatutomer for reaction mechanism studies is essential. For this reason, the present work was intended to explore the most stable and reactive guanine tautomer. To explore the most stable guanine tautomer a DFT/B3LYP method and level of theory were applied for electronic structure calculation and quantum mechanical description. Guanine was shown to exist in four different tautomeric forms (2AX 19 H, 2AX 17 H, 2AX …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 4, Issue 1, 2018 · pp. 11–20 Read article
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Capture and use CO2 with Carbon Clean Solutions(CCS)
Abstract: Abstract: India being one of the populated countries with more increasing CO2 emissions which needs affordable and scalable solutions to move towards cleaner air. Several Carbon Capture and Storage Technologies would need to be in involved and one such solution is given from the Indian Start up Carbon Clean Solutions. Key words: Carbon Capture,Storage, CO2, sustainable, technology, global warming.
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 4, Issue 1, 2018 · pp. 5–10 Read article
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MANUFACTURING OF CHLORINATED PARAFFIN WAX AND SULPHO CHLORINATED PARAFFIN WAX
Abstract: The use of chlorinated paraffin wax and sulpho-chlorinated paraffin wax in daily life is increasing day by day. They are used as flame retardant, in rubber industry, paints, adhesives, caulks, sealants, and manufacturing of different types of plastics like PVC. Here in this article, we have presented the manufacturing process for chlorinated paraffin wax (including sulpho) along with chemical reaction and mass balance. Keywords: Chlorinated paraffin wax, Manufacturing process, Mass …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 4, Issue 1, 2018 · pp. 1–4 Read article
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Preparation and Evaluation of Nano pore Faujasite Membranes
Abstract: Nano pore Faujasite zeolite membranes were synthesized by in-situ hydrothermal method on porous ceramic tubes. Hydrothermal crystallization was carried out under an autogenously pressure and at a static condition of 100 oC. Molar composition of the starting gel of Faujasite zeolite membranes were NaX: SiO2/Al2O3=10-27, Na2O/Al2O3=4-9, H2O/Al2O3=250; NaY: SiO2/Al2O3=2.5-4, Na2O/SiO2=1.08-2, H2O/Na2O=30-200. X-ray diffraction (XRD) patterns of the membranes exhibited peaks corresponding to the support and the zeolite. The crystal species …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 2, 2017 · pp. 15–24 Read article
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A Mini Review Practice of Formulations of Nanoparticles
Abstract: Nanomaterials and Nanotechnologies attract tremendous attention in recent researches. New physical properties and new technologies both in sample preparation and device fabrication evoke on account of the development of nanoscience. Various research fields including physics, chemists, material scientists, and engineers of mechanical and electrical are involved in this research. Synthesis of nanomaterials that are synonyms to quantum confined atom is an important milestone in the pursuit. Materials scientists and engineers …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 2, 2017 · pp. 1–7 Read article
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ANALYSIS OF FE AND TOTAL IRON BINDING CAPACITY (TIBC) IN CORD AND MATERNAL BLOOD SERUM
Abstract: This work explains the correlation between antenatal maternal blood and umbilical cord blood iron levels and it was not found to be closely related previously. It is observed that economic background of the patients influences the normal range of Iron binding level in Umbilical cord blood of the neonates selected from a government hospital, India. This investigation concludes that low Fe content in Umbilical cord blood makes the child susceptible …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 2, 2017 · pp. 25–37 Read article
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Chemical Synthesis and Industrial Applications of Catechu
Abstract: Kattha is acquired by crystallization in cold from the water extractives of the heartwood of Acacia catechu. The main constituents of the red heartwood are catechin and catechu tannic acid along with small proportion of brown coloring matter. It also contains tannin, flavotannin, gallotannin, hloratannin etc. (+)-Catechin is a constituent, which decreases the action of some hormones; hence “tyronorman” injected with thyroxin terminates the upsurge in basal metabolism. It has …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 2, 2017 · pp. 38–42 Read article
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Synthesis of Zeolites: An Overview
Abstract: Zeolites are microporous, aluminosilicate minerals commonly used as commercial adsorbents and catalysts. Zeolite synthesized from CFA is a minor but interesting product, with high environmental applications. Zeolites may be easily obtained from CFA by relatively cheap and fast conversion processes. This paper provides an overview on the methodologies for zeolite synthesis from CFA, and a detailed description of conventional alkaline conversion processes, with special emphasis on the experimental conditions to …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 2, 2017 · pp. 8–14 Read article
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Study of Corrosion Rate in Water Treatment Plant in Oil field
Abstract: The high cost of corrosion, the corrosion engineers concern and its reduction in oil, gas and petrochemical countries is essential about 10% of the cost of producing a barrel of crude oil cost. Corrosion rates in the world costs 42–80 cents a barrel for crude oil is produced, specific climatic conditions, history of the country's refineries and oil production are the main factors affecting the cost of corrosion in oil …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 1, 2017 Read article
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Effect of TiO2 on HER Activity of Electrodeposited Zn–Ni Coatings
Abstract: This paper demonstrates the improved electrocatalytic behavior of Zn–Ni alloy coatings for alkaline hydrogen evolution reaction (HER), due to addition of TiO2 nanoparticles into the bath. Zn–Ni alloy coatings have been electrodeposited galvanostatically on copper, with wide compositional range (2.31–7.91 wt. % of Zn) at different current densities (c.d.) between 2.0 and 5.0 A dm-2. The electrocatalytic behaviors of all coatings have been studied for alkaline HER in 1.0 M …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 1, 2017 Read article
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Successful Synthesis of Organic Molecules with Increased Conductivity and Durability
Abstract: Organic molecules are central to biological and chemical systems. Organic molecules are mainly composed of hydrogen and carbon. These constitute the building blocks for all living organism. Chemists and scientist are curious in synthesizing organic molecules that have increased conductivity and durability. Several techniques have been developed and modified to achieve this target. A novel method has been discussed for synthesis of organic molecules with enhanced conductivity and durability. Keywords: …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 2, 2016 Read article
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Identifying Chemical Combination in Consumer Products – A Report
Abstract: Chemical are both helpful as well as harmful. When used cautiously under preset and standardized protocols, they carry out several chemical reactions and synthesis. However, many of the products synthesized using chemicals have harmful effects. Many of the everyday use products such as cosmetics, detergents, toothpaste, etc., are composed of chemicals about which we are not aware of. These have several harmful side-effects and long term health issues associated with …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 2, 2016 Read article
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Controlling Catalytic Reactions-Recent Report
Abstract: Catalysts play an important role in various chemical reactions. Their prime role is to speed up the reaction. Catalysts are required in very small amounts and are not consumed during the reaction. Today, catalysts are not only required by chemists to accelerate their chemical processes but they have become a crucial part of the industrial sector as well [1]. This is because use of catalyst in accelerating the reaction rate …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 2, 2016 Read article
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Preparation and Characterization of Mixed Ligand Complexes of Cobalt(II) and Ni(II) salt of Phthalimide with Some Oxamic Acids
Abstract: The mixed ligand complexes of oxamic acids with Co(II) and Ni(II) salt of phthalimide were prepared, where oxm= N-phenyl thio urea oxamic acid(NPTUOA),m-tolumide oxamic acid (m-TOA), N-pyrrazole oxamic acid & phth= Co(II) and Ni(II) salt of phthamlimide. These all mixed ligand complexes examined by their elemental analysis, melting points, UV-visible analysis, I.R studies, magnetic susceptibility measurements and thin layer chromatography. Elemental analysis of the complexes shows 1:2 (Metal:Ligand) stiochiometry for …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 1, 2017 Read article
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Anti-tubercular activity of dioxo molybdenum (VI) metal complexes of 2-((E)-(1,5-dimethyl-2-phenyl-3-((Z)-(quinoline-8-ylimino)methyl)-2,3-dihydro-1H-pyrazole-4-ylimino)methyl)phenol
Abstract: Dioxomolybdenum(VI) complexes tetradentate ligand 2-((E)-(1,5-dimethyl-2-phenyl-3-((Z)-(quinoline-8-ylimino)methyl)-2,3-dihydro-1H-pyrazole-4-ylimino)methyl)phenol was synthesized by conventional method The ligands and their MoO22+ complexes have been characterized on the basis of elemental analysis, electronic. I.R., 1H and 13C-NMR spectral method, by their spectral studies, octahedral geometry of the complex has been proposed. On evaluation of in-vitro antitubercular activity of the ligand and dioxo Mo(VI) metal complex found that complex is more potent antitubercular agent than ligand. Keywords: anti-tubercular …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 1, 2017 Read article
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Synthesis, Spectral characterization and biocidal activities of Triphenyl antimony (V) halide and methoxide complexes
Abstract: The schiff base ligands N-mono(salicyclidene)-σ-phenylenediamine (spdH) and N-mono(2-hydroxy-1-naphthalidene)-σ-phenylenediamine (hnpdH) and their triorganoantimony (V) complexes were synthesized by conventional method, were characterized by UV, IR and 1H NMR spectral studies which proposed that in the complexes of the ligands spdH and hnpdH, antimony is seven coordinated and in sp3d3 hybridization state with pentagonal bipyramidal geometry. Keywords: halide, methoxide complexes, triphenylantimony (V)
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 3, Issue 1, 2017 Read article
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SYNTHESIS AND CHARACTERIZATION OF MIXED LIGAND COMPLEXES OF HYDROXAMIC ACIDS WITH POTASSIUM HEXATHIOCYANATO CHROMIUM (III) TETRA HYDRATE
Abstract: Some hydroxamic acids eg.[L1= benzohydroxamic acids (BHA), L2= N-phenyl– benzohydroxamic acid (NPBHA), L3= pivaloyl benzohydroxamic acid (PHA) and L4=N-phenyl-pivaloyl benzohydroxamic acid (PPHA) prepared and reacted with L’=Potassium hexathiocynato chromium (III) tetra hydrate K3[Cr(SCN)6]4H2O.The mixed ligand complexes of hydroxamic acids characterized with the help of repeated melting point, by I.R. studies, magnetic moment, molar conductance and by elemental analysis(C,H and N).The stoichiometry of the complexes were found to be 1:2(M:L) molar …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 2, 2016 Read article
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Synthesis, Spectral and Magnetic Moment Studies of Mixed Ligand Complexes of Hydroxamic Acids with Potassium Hexathiocyanato Vanadium (II) Tetra Hydrate
Abstract: Preparation and characterization of several hydroxamic acids of 3,4,5-trimethoxy benzohydroxamic acids(TMBHA), N-phenyl–3,4,5-trimethoxy benzohydroxamic acid(PTMBHA), 3,4-dimethoxy benzohydroxamic acid(DMBHA) and N-phenyl-3,4-dimethoxy benzohydroxamic acid(PDMBHA) were prepared and reacted with potassium hexathiocynato vandate (II) K4[V(NCS)6].3H2O tetra hydrate. The mixed ligand complexes of hydroxamic acids characterized with the help of repeated melting point identification, by I.R. studies, magnetic moment, molar conductance’s and by elemental analysis (C, H and N). The geometry of complexes were found …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 2, 2016 Read article
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The Thermodynamic Studies of Derivative of Thiabendazole in 1, 4 Dioxane System in the Temperature Range 303 to 323 K
Abstract: Densities, viscosities of some derivatives of thiabendazole in 1, 4 dioxane were measured in the temperature range 303 to 323 K. The viscosity was determined by John-Dole equation. The data has been used to calculate thermodynamic parameters. G and H are negative and S is positive which indicate the spontaneity of reaction according to thermodynamics. Keyword: thermodynamic parameters, free energy change, enthalpy change, entropy change
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 1, Issue 1, 2015 Read article
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Studies on Zirconium(IV) Telluroiodate: A New Heteropolyacid Based Inorganic Ion Exchange Material
Abstract: Zirconium (IV) telluroiodate has been synthesized as a new inorganic cation exchanger by adding a mixture of aqueous solution of 0.1 M potassium iodate and 0.1 M sodium tellurite to aqueous solution of 0.1 M zirconium (IV) oxychloride under varying mixing ratios at pH 1. Its ion exchange capacity for Na+ was found to be 1.85 meqg1 of dry exchanger. The material has been characterized on the basis of chemical …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article