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621 articles
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Ultrasonic Study of Binary Liquid Mixtures of Triethyl Amine With Primary Alcohols at 303.15 K
Abstract: Most of the physical properties change whenever there is a change in the composition and structure of the liquid mixture. Then non-linear dependence of the physical–chemical properties with composition has been attributed to the size, shape, and polarity of the molecules. Ultrasonic velocity is one such property which is very important for the study of molecular interactions in solution. It gives information about the extent of interaction and some other …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article
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Preparation and Characterization of Ce-Si-SBA-15 Modified With Iron
Abstract: Recently environmental concerns have driven the development of specialized catalysts to prevent polluting substances from being released into the environment. New technologies have improvised our understanding of catalytic functions as well as selectivity in order to save the energy and chemicals. Today, catalysis is the workhorse in the chemical industry with approximately >90% of the products produced in catalytic processes. In addition, life cannot exist without catalysis, as virtually all …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article
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Elucidation of Synthetic Mechanism Involved in the Conversion of Zwitterionic Clonixin to Carboxamide Side-Product
Abstract: N-(3-Chloro-2-methylphenyl)-2-oxo-1,2-dihydropyridine-3-carboxamide is obtained as a by-product during the synthesis and crystallization of Clonixin (2-(3-chloro-2-methylanilino)nicotinic acid) and its polymorphs, respectively. This conversion was unexpected and it changed the usual investigation path way enabling the formation of neutral and zwitterionic polymorphs in our study on Clonixin in contrary to studies of 2-(p-tolylamino) nicotinic acid investigation. The same conversion is checked in the other synthesized analogs such as 2-(phenylamino)nicotinic acid (PNA), 2-(methyl(phenyl)amino)nicotinic acid …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article
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Synthesis and Characterization of Cadmium exchanged Sodalite
Abstract: Cadmium derivative of chloro sodalite, has been synthesized at low temperature by hydrothermal method. The sodalite is characterized by IR, X-ray powder diffraction and SEM. The Cd derivative was obtained by facile exchange of cadmium for sodium in chloro sodalite using a solution of cadmium nitrate in Teflon autoclaves at 100oC. The IR spectra of parent gallo silicate chloro sodalite and cadmium exchanged chloro sodalites shows three kinds of IR …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article
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Preparation and Characterisation of the Schiff’s Base Complex [Pt(dpq)Cl2]
Abstract: Preparation of platinum complex [Pt(dpq)Cl2] and characterization of the complex by IR, UV, CHN and NMR techniques. DPQ ligand is obtained by 1,10 phenanthroline made react with NaBr, nitrating mixture followed by ethylenediamine in ethanol. Keywords: DPQ, intercalator, platinum complex, Schiff’s base
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 1, Issue 2, 2015 Read article
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Development of Geo-Polymer based Light Weight Bricks
Abstract: Light weight geopolymer bricks were developed during this study. The mix was made with lime sodium silicate and fly ash as ingredients. A maximum shrinkage was observed at CaO lime ratio of 1.0. Bulk densities were also lower at the ratio of 1.0. The maximum cold crushing strength (CCS) value was found at the ratio of 0.745. Increase in mix water decreased the strength. Water content of 24% is recommended …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 1, Issue 1, 2015 Read article
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Design and Pinch Analysis of Styrene Production Process Using Aspen HYSYS and Aspen Energy Analyzer
Abstract: This paper presents the design and energy analysis of styrene production process. Process flow diagram is designed using Aspen HYSYS. Styrene product obtained is of purity 73% and further purity is recommended. Pinch analysis is applied to the process plant by using Aspen Energy Analyzer, as a part of that in the first step all the stream data is extracted, in the second step heat exchanger networks (HEN) is developed …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 1, Issue 1, 2015 Read article
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Mechanical Studies and Thermal Kinetics of Isoniazid Crystals
Abstract: Single crystals of isoniazid were crystallized by slow solvent evaporation method. The crystal structure was confirmed using single crystal X-ray diffraction analysis. Micro hardness was estimated and work hardening coefficient and Newtonian resistance pressure of the crystal were determined. Kinetic analysis of the thermogravimetric data was carried out by using Coats-Redfern relation. Activation energy, frequency factor and order of reaction were also calculated. Arrhenius equation for isoniazid is k=0.43×105e–79103/RT mol–1s–1. …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 1, Issue 1, 2015 Read article
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Applications of Separation of Materials
Abstract: The main aim in our work deals with the preparation of series of new bio compounds that have interesting in bio and biomedical fields, pharmaceutical drugs, medicinal biochemistry and in other fields also. All compounds have wide applications and the prepared bio compounds were prepared through many steps with various conditions like azetidine, imidazole, thiazine, oxazepine , diazepine , tetrazole. The structure of the newly synthesized compounds were monitored by …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 2, 2019 · pp. 20–24 Read article
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Different type of catalysts used in the Baylis-Hillman reaction
Abstract: The Baylis-Hillman reaction in the present-day version is an atom-economic carbon-carbon bond-forming reaction between the α-position of the activated alkenes and carbon electrophiles under the influence of a catalyst or catalytic system offering diverse classes of densely functionalized molecules. If the substrate contains both the activated alkene and electrophile components in appropriate positions, there is the possibility of developing an intramolecular version of this reaction leading to the synthesis of …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 2, 2019 · pp. 30–37 Read article
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Chromatographic Techniques with Biological Applications
Abstract: Chromatography is kind of a number of purification performances distinct as differential relocation from a slight preliminary zone. Electrophoresis is another member of this group. In this case, the driving force is an electric field which exerts different forces on solutes of different ionic charge. The resistive force is the viscosity of the nonflowing solvent. The combination of these forces yields ion mobilities peculiar to each solute. Chromatography technique for …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 2, 2019 · pp. 25–29 Read article
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Millard Reaction: The Chemical Reaction of Browning, Flavoring and Aroma Through the Science of Cooking.
Abstract: The Maillard reaction is a step in the formation of advanced glycation endproducts (AGEs). It is tracked by measuring pentosidine. Even though the Maillard reaction has been studied most extensively in food science, it has also displayed and shown correlation in many different diseases in the body of human being, especially in degenerative eye diseases. In normal conditions, these diseases are due to the accumulation of advanced glycation endproducts (AGEs) …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 2, 2019 · pp. 9–19 Read article
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Predictive Modelling of a Bioreactor for the Production of Ethanol Using Palmwine
Abstract: This research focuses on the feasibility of biochemical technology with yeast cells (Sacccharomycees cerevisiae) for continuous ethanol production from palm wine. This was carried out in a non-isothermal batch reactor at constant room temperature. 1.5L of palm wine solution was reacted with dry active baker’s yeast until reaction was completed. Biomass, ethanol and glucose concentration were sampled every two hours, and kinetic rate parameters for the fermentation calculated using concentration/time …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 2, 2019 · pp. 1–8 Read article
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Studies on corrosion mechanisms of steel wire ropes
Abstract: Degeneration of lubrication by seepage of water to core of ropes produces corrosion to change relevant properties. Corrosion of wire ropes in suspender of cross-sea bridges has induced from sulfur dioxide present in environment. Stress corrosion accident of steel wire in coalmine has studied by stress corrosion behaviors of high strength steel wires in mine trickling water. Keywords Steel, Rope, Corrosion, Fracture, Mine water, Tensile test, Stress corrosion crack
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 1, 2019 · pp. 28–35 Read article
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ISONIAZID STABILIZED TUNGSTEN TRICARBONYL COMPLEX: A NEW CO-RELEASING MOLECULE WITH ANTIBACTERIAL ACTIVITY
Abstract: Transition metal carbonyl complexes substituted with biologically active ligand can act as CO-releasing molecules which have beneficial roles including antimicrobial activity. Careful choices of ancillary ligand such as isoniazid help in eliminating issues of toxicity that may arise from drug substrates. Substitution reaction of tungsten hexacarbonyl with isoniazid in the presence of trimethylamine N-oxide under nitrogen atmosphere was carried out at ambient temperature for 72 hrs. The product was characterized …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 1, 2019 · pp. 36–43 Read article
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Review in Chemical Structures of Common Compounds
Abstract: Our review deals with chemical structures of common chemical compounds which collected for interesting , There are several different names of chemical compounds , but for example when you for phenol derivative or amine derivatives , you are referring to a great tables from compounds in this field., There are millions of known chemical compounds yet to be discovered due to the great variety of compounds a naming system was …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 1, 2019 · pp. 1–15 Read article
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Spectrophtometric Study of Catalysed Oxidation of Some Cyclic Alcohols by N-bromophthalimide
Abstract: The spectrophotometric kinetic investigation of cyclohexanol and cycloheptanol catalysed by Keggin type anion [PW12O40]3- with N-bromophthalimide have been carried out in 30% acetic acid medium in absence of mercuric(II) acetate and in presence of sulphuric acid. The observed kinetic data was used for the justification of Beer-Lambert law. The reactions follow a fractional-order with respect to cyclic alcohols, PTA catalyst and first-order with respect to oxidant NBP. The added H+ …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 1, 2019 · pp. 44–50 Read article
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Presence of Chemical Ions in Raw and Treated Water
Abstract: Dhaka water supply and sewerage authority utilizes a section of the DND canal from Sarulia to Kajla to convey raw water from the Shitalakhya river to the water treatment plant at Saidabad. Raw water quality is poor mostly in the dry season. High heavy metal concentration in the water at the intake point is found. Aluminum (Al), Cadmium (Cd), Lead (Pb), and Mercury (Hg) are detected in river water which …
Published in International Journal of Green Chemistry · Vol. 5, Issue 2, 2019 · pp. 9–21 Read article
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Use of the electroflotation for oil spill or oil products cleanup from sea or waste water as a new environmental technology
Abstract: Among the existing today methods of cleaning of oil spill and oil products from sea or waste water most perspective for cost-effective and highly effective properties is the electroflotation. However, main problem in the all existing electroflotation methods of cleaning is the increase of the saltiness of the space near the cathode as a result of passing of the electric current through the sea or waste water that covers cathode’s …
Published in International Journal of Green Chemistry · Vol. 5, Issue 2, 2019 · pp. 22–29 Read article
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Heavy metal concentrations in two mangrove species grown in the UAE region and use of phytoremediation technology
Abstract: The mangrove vegetation of Eastern region of UAE, rhizosphere root, leaf, stem and soil sediments of two mangrove types studied for the levels of Cr, Cu, Cd, Mn, Ni, Zn and Pb in the eastern Emirates region. The analysis was carried out with FAAS spectroscopy using microwave digestion technique. The two mangrove plants are most abundant in this region. the bioconcentration factor (BCF) > 1 metal content was quantized. It …
Published in International Journal of Green Chemistry · Vol. 5, Issue 2, 2019 · pp. 1–8 Read article