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806 articles for “TEM”
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Recovery of Succinic acid by Reactive Extraction using Tri-n-octylamine in 1-Decanol: Equilibrium Optimization using Response Surface Method and Kinetic studies
Abstract: Reactive extraction is a promising technique for the recovery of organic acids from aqueous streams. Succinic acid, is a white, odorless solid dicarboxylic acid, and is a precursor for some specialized polyesters. Present paper presents an optimization study of reactive extraction of succinic acid equilibrium studies from aqueous solutions using Tri-n-octylamine in 1-Decanol using response surface methodology including reaction kinetics in a stirred cell. Extraction efficiency (Y), a response function …
Published in International Journal of Chemical Separation Technology · Vol. 2, Issue 2, 2016 · pp. 1–14 Read article
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Hydrogenation of dimethyl-nitrobenzene to dimethyl-aniline in a three-phase Reactor
Abstract: The liquid-phase catalytic hydrogenation of dimethyl-nitrobenzene (DN) to Dimethyl-aniline (DA) was carried out in ethanol using 5% Pd/C as a catalyst. The effects of hydrogen partial pressure (400–1000 kPa), reaction temperature (343–403 ), catalyst loading (5–15 g/lit), speed of stirring range (200-800 rpm) and dimethyl-nitrobenzene concentration (0.12–0.75 mol/lit) on the hydrogenation of dimethyl-nitrobenzene and the yield of Dimethyl-aniline have been studied. Dimethyl-aniline was the only reaction product, generated through the …
Published in International Journal of Chemical Separation Technology · Vol. 3, Issue 2, 2017 · pp. 1–13 Read article
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Electrolytic Deposition of Zn–Ni Alloy from Acidic Sulphate Bath and Their Characterization
Abstract: A bath containing ZnSO4.7H2O, NiSO4.7H2O, thiamine hydrochloride (THC) and citric acid (CA) has been proposed. Bright Zn–Ni alloy coatings were developed galvanostatically onto mild steel (MS) and their corrosion resistance and other physical properties were studied. THC was found to improve the brightness and homogeneity of the deposit. The dependency of bath composition, current density (c.d.), pH and temperature, agitation on wt.% Ni were tested. Deposition was carried out under …
Published in International Journal of Chemical Engineering and Processing · Vol. 2, Issue 2, 2016 · pp. 19–32 Read article
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Kinetic and Thermodynamic Studies of Adsorption of Pb (II) by Using Ferrous Sulphide as an Adsorbent
Abstract: Poisoning of lead is causing a serious threat to the environment. In the present study the adsorption behaviour of lead was studied in detail by ferrous sulphide in granular form. Ferrous sulphide has the magnetic properties and makes it a better candidate for lead removal. Batch adsorption experiments were carried out by varying different process parameters such as contact time, adsorbent dose, pH, and temperature. Lead adsorption by ferrous sulphide …
Published in International Journal of Chemical Engineering and Processing · Vol. 2, Issue 2, 2016 · pp. 33–41 Read article
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Response Surface Methodology to Optimize Deproteinization of Green Crab Shells (Carcinus maenas)
Abstract: The crab shells are used as a feedstock for the extraction of either chitin or chitosan and other bioactive materials such as dyes and proteins. The optimum conditions are required for a process development for an effective separation of chitin. The most important parameters for deproteinization of green crab shells have identified the concentration of NaOH, temperature and time of contact. The optimum conditions for deproteinization of Green crab shells …
Published in International Journal of Chemical Engineering and Processing · Vol. 3, Issue 2, 2017 · pp. 30–37 Read article
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Development of dynamic model for alkaline water electrolyser: Application to disturbance analysis
Abstract: A dynamic model of an alkaline water electrolyser plant has been developed to study its time dependent behaviour when it is subjected to dynamically varying inputs like changing electrolyte flow, inlet temperature, pressure, current, voltage. Such dynamic conditions are expected to arise during start up and shut down and also when the electrolyser is coupled to a nuclear or renewable electricity source, both of which exhibit time dependent power output …
Published in International Journal of Chemical Engineering and Processing · Vol. 5, Issue 1, 2019 · pp. 11–23 Read article
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Plant Extracts Volume Effects on the Corrosion of MCS Metal Sample using Water-Based as an Inhibitor
Abstract: The effect of water-based extracts of two different samples was examine with respect to volume on the characteristics of MCS metal corrosion inhibition. This research revealed that volume of extracts is a controlling factor in terms of metal corrosion inhibition as demonstrated by the two different water-based extracts investigated. Increase in the inhibiting substance (water-based extract) in terms of volume resulted to decrease in the rate of corrosion of the …
Published in International Journal of Chemical Engineering and Processing · Vol. 9, Issue 1, 2023 · pp. 1–8 Read article
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Bioethanol Production from Corncob Cellulosic Biomass: RSM and ANN based Optimization for Dilute Acid Pretreatment
Abstract: To increase the yield of fermentable sugars, the complexity of lignocellulosic biomass requires a pretreatment method. Dilute acid hydrolysis was used to efficiently pretreatment corn cobs. The aim of this study was to characterize corncob and investigate the effect of process parameters on total reducing sugar (TRS) yield during dilute acid hydrolysis pretreatment of corncob biomass. The morphology and microstructure of the samples were examined using an X-ray diffraction machine, …
Published in International Journal of Chemical Engineering and Processing · Vol. 9, Issue 2, 2023 · pp. 16–34 Read article
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Pyrolysis Characteristics and Isoconversional kinetics of kusum deoiled seedcake.
Abstract: The pyrolysis characteristics and kinetics of kusum de-oiled seed cake were conducted using a Thermo gravimetric analyzer. Thermogravimetric analysis of biomass was carried out at three different heating rates of 10, 20, 30, ̊ C/min from 28 ̊ C to 1000 ̊ C under N2 atmosphere. The results indicated that the biomass was decomposed in the temperature range of 270 ̊C to 520 ̊ C and further decreased when temperature …
Published in International Journal of Environmental Chemistry · Vol. 2, Issue 2, 2016 · pp. 9–17 Read article
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Assessment of the Physiochemical Parameters of Aluu Crude Oil Polluted Soil Environment in Niger Delta.
Abstract: Investigation was carried out to examine the effect of Crude oil contamination of Aluu soil and some of the physiochemical parameters. The physiochemical parameters studied were temperature, pH value, electrical conductivity and available phosphorus. The result obtained revealed the significant effect of the crude oil contamination on the physicochemical parameter investigated. The statistical analyses used were analysis of variance (ANOVA) and regression analysis. The time has effect on temperature and …
Published in International Journal of Environmental Chemistry · Vol. 5, Issue 2, 2019 · pp. 30–37 Read article
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Nanocoating and Electrospraying Techniques Used for Corrosion Mitigation of Aluminum in Nitrogen dioxide Environment
Abstract: Nitrogen gas absorbs moist air to produce nitric acid. It develops acidic medium for aluminum. It forms a corrosion cell on the surface of aluminum. The formation of corrosion cell is written as: Al|Al+3||H+|H2 thus Corrosion reactions accelerate on aluminum surface and Al is oxidized into Al+3 and the H+ ions is reduced into H2. This acid produces various forms of corrosion in aluminum like galvanic, pitting, stress, crevice, blistering, …
Published in International Journal of Environmental Chemistry · Vol. 6, Issue 2, 2020 · pp. 20–31 Read article
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Environmental Impacts of Water Pollution
Abstract: Water is required for all life forms to exist. Water is essential for agriculture, industry, fishing, and tourism, among other things, in addition to household uses. Water availability has decreased as the world's population, urbanization, and industrialization have increased. The quality of the water used is also deteriorating as it becomes increasingly polluted. You've probably heard about some of the health harm or adverse consequences of water contamination. This teachable …
Published in International Journal of Environmental Chemistry · Vol. 7, Issue 2, 2021 · pp. 46–49 Read article
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Effective Utilization of Agricultural Waste for Removal of Heavy Metals from Waste Streams
Abstract: The progress of industrialization and urbanization poses a great threat to the comfort of people's lives. The production and disposal of large amounts of toxic pollutants have severely polluted our environment. The most hazardous contaminants in soils and surface waters include some organic compounds, like synthetic dyes (SD) and toxic substances (heavy metals). It is of great interest worldwide due to its toxicity to many organisms. An important topic is …
Published in International Journal of Environmental Chemistry · Vol. 8, Issue 2, 2022 · pp. 1–11 Read article
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The Improvement of Polyvinyl Chloride Synthesis Using Different Approaches
Abstract: Polyvinyl chloride (PVC) is produced by the polymerization of the vinyl chloride monomer either by direct chlorination of olefins or by addition of hydrogen chloride to acetylene. The polymerization conditions are: heat, peroxides or oxidizing agents with basic structure as -CH2CHCl.CHCl-CH2.CHCl-. Polyvinyl chloride is a thermoplastic and its plasticity can be increased by incorporating ‘plasticizers’ of relatively low molecular weight organic materials during molding or extrusion. PVC has high hardness …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 2, 2020 · pp. 48–52 Read article
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Several Phases of Binary Liquid Mixture
Abstract: The system’s overall composition, heat, and stress can all be changed independently. Instead of using parameters like the coordinates of a three-dimensional phase diagram, we often generate a twodimensional phase transformation that is either a thermal diagram at a specified pressure or its composition graph at a fixed temperature. The location of the system points on one of these diagrams correlates to a certain heat, stress, and normal phenomenon. As …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 8, Issue 1, 2022 · pp. 30–34 Read article
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Nuclear waste heat and renewable energy derived hydrogen: Preliminary feasibility analysis
Abstract: Hydrogen, a possible carbon free energy resource of the future, can be obtained in a sustainable manner from abundantly available resource like water through low temperature, low pressure water electrolysis. This work examines the techno-economic feasibility aspects of a water electrolysis based hydrogen production plant of capacity 1000-10000 Nm3/hr, when coupled with a typical nuclear power plant in India and renewable energy resources in novel ways. The nuclear waste heat …
Published in International Journal of Renewable Energy and its Commercialization · Vol. 4, Issue 2, 2018 · pp. 7–31 Read article
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Continuous Renewable Energy Generation by Solar Radiation
Abstract: The world is seeing a changing trend from conventional cooking system to most reliable and predominant solar cooking system which is going wild commercially. This ideal attempts a heat energy storage for power generation in which a Molten Salt is proposed for Thermal Energy Storage for Concentrating Solar cooking systems. In the concept numerous large, flat, sun-tracking mirrors, known as trough are used which focuses sunlight onto a receiver at …
Published in International Journal of Renewable Energy and its Commercialization · Vol. 4, Issue 2, 2018 · pp. 32–41 Read article
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Effects of Compatibilizer and Paper Sludge Content on the Performances of Thermoplastic Polymer Composites
Abstract: One of the environmental issues affecting third-world countries is the economic use of lignocellulose waste, which is now being researched. Paper sludge (PS) composites will allow for the effective use of a waste material that is currently burned or buried, as well as the ability to lower the cost of the composite that is created. In this study, the mechanical and thermalcharacteristics of environmentally friendly composites constructed from PS-reinforced recycled …
Published in International Journal of Renewable Energy and its Commercialization · Vol. 8, Issue 2, 2022 · pp. 10–21 Read article
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Characterization and Kinetic Study of Sugarcane Bagasse for the Production of Bio-oil Over Monodispersed Fe2 O3 and ZSM-5 Composite
Abstract: The shortage and price scramble of fossil fuels accompanied by vast CO2 emissions have triggered a worldwide search for alternative and sustainable resources. Wind, solar, geothermal, biomass, and water are the most commonly used alternative energy sources. The biomass residues are typically at low cost and readily availabile, and has been used as feedstocks for synthesis of renewable energy. To produced the bio-fuels from biomass residues, several reaction pathways categorized …
Published in International Journal of Renewable Energy and its Commercialization · Vol. 9, Issue 2, 2023 · pp. 1–13 Read article
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Simplified Models for Some Thermodynamic Properties of Saturated Water in a Pressurized Water Reactor
Abstract: The properties of water and steam in a pressurized water reactor (PWR) need constant monitoring to understand what goes on in the PWR. Such properties include the thermodynamic properties, namely, specific volume, specific enthalpy, specific entropy and specific heat. This work is focused on calculating these properties of saturated water by using a simplified model within the temperature range that is applicable to PWR. The model parameters for each property …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 1, Issue 1, 2015 · pp. 10–15 Read article