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33 articles for “transition metals”
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TiO2 Doped with Noble Metals and Transition Metals: A Review
Abstract: This review article investigates advances in the research of nanomaterials based on titanium dioxide (TiO2) doped with noble metals and transition metals. Initially, we provide an overview of the theory behind TiO2 as the base material and discuss the fundamental principles of nanomaterial doping. Next, we delve into studies on noble metal doping, highlighting recent research that explores the incorporation of noble metals such as gold (Au), silver (Ag), and …
Published in International Journal of Metallurgy and Alloys · Vol. 9, Issue 1, 2023 · pp. 1–12 Read article
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Assessing trends in Speciation of First-Row Transition Metals in Children's Playgrounds of Owerri, Nigeria
Abstract: Chemical species of metals affect toxicity but trends of these metals species in soils are less studied. This study examined the trends and variability of species of metals in soils from playgrounds within Owerri. Eighty-one composite soil samples from nine playgrounds were collected in dry and rainy season to reflect spatio-seasonal variability. Samples were characterized by standard methods in triplicates and then extracted sequentially. Concentrations of metal species were determined …
Published in International Journal of Green Chemistry · Vol. 11, Issue 1, 2025 · pp. 28–45 Read article
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Synthesis, characterization of Schiff base and its pH metrically studies of transition metal complexes of N'-(3, 4-dihydroxybenzylidene) isonicotinohydrazide.
Abstract: Schiff reaction is one of the versatile reaction widely used in organic synthesis focused on the discovery & development of isoniazide Schiff base derivative N’(3,4-Dihydroxy benzylidene isonicotinohydrazide) have been reported in presence of 0.01g molecular iodine catalyst stirring give fast product & good yield. The synthesized compound is characterized by FTIR & H-NMR analysis. For the development of coordination chemistry Schiff base & metal ion having played most important role, …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 6, Issue 2, 2020 · pp. 39–47 Read article
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Doping and Its Impacts on the Properties of ZnO Nanocrystals: A Brief Review
Abstract: Research on zinc oxide (ZnO) has surged in recent years due to its extensive range of applications because its unique physical and chemical properties make it ideal for various uses, including acoustic devices, photocatalysis, pharmaceuticals, light-emitting diodes, solar cells and antibacterial agents. ZnO nanoparticles are particularly notable for their biocompatibility, low toxicity and stability, making them suitable for drug delivery and antiviral applications. The versatility of ZnO has led to …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 10, Issue 1, 2025 · pp. 8–25 Read article
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Studies of Nano-catalyst
Abstract: Nano-catalysts are studied in this article to compose single allocate transitional or novel atom on substrate in place of usual nano-configured atoms aligned to Pt, Pd, Ru, Rh and Ir. Acid to base proposition subjected to form stable catalyst composes from transition metals in place from expensive novel metals. In novel metal nano-cluster catalyst compose has selected scheme at rest with no or reverse consequence to give rise well defined …
Published in International Journal of Nanomaterials and Nanostructures · Vol. 7, Issue 1, 2021 · pp. 13–18 Read article
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Sustainable Hydrogen Solutions: Beryllium-Based Complexes and Catalysts for Efficient Energy Storage and Production
Abstract: This study explores the potential of beryllium (Be) and transition metal (TM) complexes in hydrogen storage and production, focusing on the hybridization of atomic orbitals to form dihydrogen complexes within nanostructured materials. We analyze the binding energies and adsorption characteristics of H₂ molecules in Be-dihydrogen complexes and compare them with TM-dihydrogen complexes. The findings indicate that Be can effectively bind H₂ at room temperature, making it a promising candidate for …
Published in International Journal of Energetic Materials · Vol. 10, Issue 2, 2024 · pp. 1–5 Read article
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Effect of impurity metal (Fe, Co, Ni) on WSex as good hydrogen evolution catalyst
Abstract: Transition metal chalcogenides are recognized as a category of very promising non-expensive and earth-abundant catalysts for Hydrogen evolution reaction (HER) catalysts. Many literature reports appeared recently on metal selenides due to excellent phyco-chemical properties and for HER, this mini review attempt to give some insight on effect of Fe, Co, Ni to WSex toward efficiency of HER. From the literature report showed that presence of impurities activity with WSex following …
Published in International Journal of Energetic Materials · Vol. 6, Issue 2, 2020 · pp. 31–36 Read article
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Preparation and Characterization of Ce-Si-SBA-15 Modified With Iron
Abstract: Recently environmental concerns have driven the development of specialized catalysts to prevent polluting substances from being released into the environment. New technologies have improvised our understanding of catalytic functions as well as selectivity in order to save the energy and chemicals. Today, catalysis is the workhorse in the chemical industry with approximately >90% of the products produced in catalytic processes. In addition, life cannot exist without catalysis, as virtually all …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 2, Issue 1, 2016 Read article
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Toxicity of Chromium Metal and its impact on Human health
Abstract: Chromium, a transition metal, plays a vital role as a trace element essential for human metabolism. Its presence in various oxidation states is notable, with the trivalent (Cr(III)) and hexavalent (Cr(VI)) forms being the most common and biologically significant. While Cr(III) is recognized for its involvement in insulin signaling and glucose metabolism, Cr(VI) stands out for its toxicity, posing significant risks to both human health and the environment. The extensive …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 9, Issue 2, 2023 · pp. 16–20 Read article
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Nanostructured Metal Oxides as Promising Electrode Materials for Microbial Fuel Cells
Abstract: Microbial fuel cells (MFCs) are emerging as a promising technology for generating sustainable energy from organic waste materials. One of the key challenges in developing efficient MFCs is the selection of suitable electrode materials. In recent years, nanostructured metal oxides have gainedconsiderable attention as electrode materials for MFCs due to their unique structural and electrochemical properties. This review highlights the recent progress in the development and application of various types …
Published in International Journal of Applied Nanotechnology · Vol. 8, Issue 2, 2022 · pp. 23–30 Read article
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COMPLEXATION AND ANTIBACTERIAL STUDY OF 1,3,4-OXADIAZOLE DERIVATIVE
Abstract: New metal complexes of Zn(II),and Ni(II) have been synthesized by reacting metal solutions with the ligand 2,5-substituted 1,3,4-Oxadiazoles in alcoholic medium. Molecular formulae of the complexes were determined and are further characterized by IR spectroscopy, magnetic susceptibility and molar conductance studies. Since two nitrogen atoms coordinate to the metal center, the ligand is termed as bidentate ligand.KEY WORDS: Complexes, Ligands, Transition metal complexes, Oxadiazoles.
Published in International Journal of Green Chemistry · Vol. 6, Issue 2, 2020 · pp. 26–29 Read article
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Synthesis and Biological Evaluation of a Novel Schiff Base Ligand [(E)-2,4-Dichloro-6-(1-((4-Fluorophenyl) iminoethyl)phenol] and Its Metal Complexes
Abstract: The study involved the synthesis and characterization of a novel bidentate Schiff base ligand, [(E)-2,4-dichloro-6-(1-((4-fluorophenyl) iminoethyl) phenol)], derived from 1-(3,5-dichloro-2-hydroxyphenyl) ethanone and 4-fluoroaniline. Transition metal salts (Co (II), Cu (II), Fe (II), Zn (II), Ni (II), Mn (II), Ag (II), Cd (II), Hg (II), and Pd (II)) were used to synthesize metal complexes. The chemicals used were of analytical grade, and solvents were distilled before use. Characterization involved UV, IR, …
Published in International Journal of Analytical and Applied Chemistry · Vol. 10, Issue 1, 2024 · pp. 26–35 Read article
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Aromaticity-Guided Synthesis and Reactivity of Heterocyclic Compounds: Structural Insights and Applications
Abstract: The concept of aromaticity serves as a fundamental framework for understanding the structural and electronic characteristics of heterocyclic compounds, which play a crucial role in modern synthetic chemistry. Aromatic compounds, characterized by cyclic planar systems with delocalized π-electrons, follow the Hückel rule, conferring significant stability to heterocyclic structures. The incorporation of heteroatoms, such as nitrogen, oxygen, and sulphur, within these rings profoundly influences electron distribution, molecular reactivity, and synthetic pathways. …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 11, Issue 2, 2026 · pp. 1–7 Read article
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A Comprehensive Review of Nanostructures:From Design to Real-World Applications
Abstract: Nanostructures represent a frontier in modern nanotechnology, offering uniquephysical, chemical, and biological characteristics that set them apart from theirlarger-scale counterparts.This article talks about the most studied and usednanostructures, such as nanoparticles, nanowires, nanotubes, nanorods, quantumdots, and 2D materials like graphene and transition metal dichalcogenides(TMDs). We talk about how they are made, what they look like, and how theywork, focussing on how they are used in electronics, energy storage, catalysis,biomedicine, and …
Published in International Journal of Nanomaterials and Nanostructures · Vol. 11, Issue 2, 2025 Read article
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Synthesis, Crystal Growth and Characterization of Bismuth Doped Potassium Hydrogen Phthalate Crystal (Khp): A Nlo Material
Abstract: To create single crystals using the Slow Evaporation Solution Growth Technique (SEST), equimolar composition of the transition metal (Bi) as Bismuth nitrate is added to Potassium Hydrogen Phthalate (KHP) (1:1) at ambient temperature. The following analysis is then performed on the single crystals that have formed. Equimolar doping-induced structural distortion in the crystals is confirmed by the FT-IR Spectra. The TGDTA study reveals the purity of the material and no …
Published in International Journal of Composite Materials and Matrices · Vol. 10, Issue 1, 2024 · pp. 19–27 Read article
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Green Synthesis, Characterization and Antimicrobial Studies of Ni(II) and Cu(II) Schiff Base Complexes
Abstract: Solvent-assisted mechanochemical reaction was used to synthesize new transition metal complexes of Ni(II) and Cu(II) with Schiff base ligand (H2L) obtained from condensation of 2-hydroxy-1- napthaldehyde with 2 aminobenzimidazole. Melting point/decomposition temperature, solubility test, FT-IR, powder x-ray analysis, conductivity measurement, magnetic susceptibility, elemental microanalysis, and UV/VIS spectral investigations were used to characterize the Schiff base and complexes. The complexes are of varied colours and have sharp melting points, and they …
Published in International Journal of Green Chemistry · Vol. 8, Issue 1, 2022 · pp. 9–18 Read article
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ISONIAZID STABILIZED TUNGSTEN TRICARBONYL COMPLEX: A NEW CO-RELEASING MOLECULE WITH ANTIBACTERIAL ACTIVITY
Abstract: Transition metal carbonyl complexes substituted with biologically active ligand can act as CO-releasing molecules which have beneficial roles including antimicrobial activity. Careful choices of ancillary ligand such as isoniazid help in eliminating issues of toxicity that may arise from drug substrates. Substitution reaction of tungsten hexacarbonyl with isoniazid in the presence of trimethylamine N-oxide under nitrogen atmosphere was carried out at ambient temperature for 72 hrs. The product was characterized …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 1, 2019 · pp. 36–43 Read article
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Survey on Semicarbazide and Thiosemicarbazide Derivatives
Abstract: This review insurances around semicarbazide and thiosemicarbazide with derivatives throughpresentation of their preparation methods, reactions like cyclization processes. Thiosemicarbazonesand semicarbazones are an important class of ligands for the synthesis of transition metal complexeswith applications in medicine and electrochemistry, also in organic chemistry fields., Tumor is amalignant in addition invasive development or cancer, particularly of epithelium derivation, whichinclines to recur after erasure also may metastasize to other places. It befalls due …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 7, Issue 1, 2021 · pp. 51–57 Read article
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Efficiency of Super Heterodyne Fabricated Matter
Abstract: Nano fabrication efficacy has been efficient features to the system of Bluetooth low energy (BLE) from assigned overcome from discrete-time (DT) superheterodyne receiver (RX). Additional characteristic of DT-RX system is for applicability to internet-of-things (IoT), commercial Bluetooth and 2G cellular radios, while alternative to software-defined radio applicability. Implicative produce has furnished evolve of programmable capacitor for switched-capacitor (SC) structure. Program has added to flex digitally intensive scriptive system, which has …
Published in International Journal of Microelectronics and Digital integrated circuits · Vol. 7, Issue 2, 2021 · pp. 1–8 Read article
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Effects of Gate Oxide Thickness and Its Dielectric Strength in WS2 Based TMDFET
Abstract: This paper presents the numerical simulation of transition metal dichalcogenide based field effect transistor (TMDFET). Here we have studied the transfer characteristic, ION/IOFF ratio, subthreshold slope of TMDFET by varying oxide thickness and its dielectric strength dependence performance. The channel material used for field effect transistor is tungsten disulfide (WS2). To calculate the transfer (input) characteristics, we use Non Equilibrium Greens Function (NEGF). Results are achieved by solving the Poisson’s …
Published in International Journal of Energetic Materials · Vol. 5, Issue 1, 2019 · pp. 14–20 Read article