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38 articles for “isotherms”
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To Screen for Citrus Tristeza Virus & Potato Viruses in Stems and Leaves of Plant Samples
Abstract: For centuries, viruses have been known to cause four diseases in almost every plant species and inflict devastating economic losses every year. With the emergence of new infectious diseases via outbreaks, rapid detection and accurate identification with the means of high throughput technology becomes all the more important. The development of numerous diagnostic methods such as ELISA and Lateral Flow Assays which work on the principle of antigen antibody interaction …
Published in International Journal of Plant Biotechnology · Vol. 8, Issue 2, 2022 · pp. 31–51 Read article
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Equilibrium and kinetic studies on reactive extraction of lactic acid
Abstract: Abstract: Lactic acid has became a growing requirement in various fields so reactive extraction has been employed to recover by using tri pentyl amine and tertiary butyl amine in different diluents (1-octanol, chloroform and dimethylene chloride). Physical and chemical equilibrium isotherms, KD, loading ratio (Z) were measured through equilibrium studies for (1:1) and (2:1) acid amine complex formation at room temperature. By conducting kinetic studies in batch type reactive system …
Published in International Journal of Chemical Separation Technology · Vol. 4, Issue 2, 2018 · pp. 35–46 Read article
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Nanocoating and Electrospraying Techniques Used for Corrosion Mitigation of Aluminum in Nitrogen dioxide Environment
Abstract: Nitrogen gas absorbs moist air to produce nitric acid. It develops acidic medium for aluminum. It forms a corrosion cell on the surface of aluminum. The formation of corrosion cell is written as: Al|Al+3||H+|H2 thus Corrosion reactions accelerate on aluminum surface and Al is oxidized into Al+3 and the H+ ions is reduced into H2. This acid produces various forms of corrosion in aluminum like galvanic, pitting, stress, crevice, blistering, …
Published in International Journal of Environmental Chemistry · Vol. 6, Issue 2, 2020 · pp. 20–31 Read article
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Predictive Modelling of a Bioreactor for the Production of Ethanol Using Palmwine
Abstract: This research focuses on the feasibility of biochemical technology with yeast cells (Sacccharomycees cerevisiae) for continuous ethanol production from palm wine. This was carried out in a non-isothermal batch reactor at constant room temperature. 1.5L of palm wine solution was reacted with dry active baker’s yeast until reaction was completed. Biomass, ethanol and glucose concentration were sampled every two hours, and kinetic rate parameters for the fermentation calculated using concentration/time …
Published in International Journal of Chemical Synthesis and Chemical Reactions · Vol. 5, Issue 2, 2019 · pp. 1–8 Read article
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Thermal Decomposition Kinetics of Mefenamic Acid Crystals
Abstract: Single crystals of mefenamic acid were crystallized by gel growth method for the first time in literature. Crystal structure was confirmed using single crystal X-ray diffraction analysis. Kinetic analysis was made from the isothermal thermogravimetric analysis/differential thermal analysis (TGA/DTA) data using Coats–Redfern (CR) relation. Thermodynamic parameters were also determined. Arrhenius equation for mefenamic acid is k = 0.28 × 109 e–116551/RT mol–1s–1. Keywords: kinetic analysis, mefenamic acid, thermal analysis
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 2, Issue 1, 2016 · pp. 21–24 Read article
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Corrosion Protection of Copper Metal by Nanocoating in Nitrogen dioxide Environment
Abstract: Nitrogen dioxide is an acidic gas. It absorbs moisture to produce nitric acid. It creates corrosive medium for copper metal. It forms corrosion cell on the surface of copper and accelerate corrosion reactions. The corrosion cell formation is written as: Cu|Cu2+||H+|H2 thus corrosion reactions start and copper is oxidized into Cu2+surface and it is oxidized into Cu2+ whereas H+ ion is reduced into H2. Nitric acid environment copper exhibits galvanic, …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 8, Issue 1, 2022 · pp. 1–11 Read article
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Thermodynamic and Kinetic Characterization of Aluminum Corrosion and Inhibition Adsorption of Vernonia Amygdalina Fruit Extract IN 0.5N H2SO4
Abstract: Anti-corrosive efficacy of ethanolic extract of Vernonia amygdalina fruit extract on corrosion of aluminum in 0.5N H2SO4 acidic solution was explored by mass loss measurement at rise in temperature between 303-343 K for 24 hours immersion period. The I.E. (η%) has been noticed prominently high (62.92%) at concentration 0.45% at 303 K. An inhibitor adsorption on the surface aluminum have been found to be best fitted Langmuir adsorption isotherm. It …
Published in International journal of Thermodynamics and Chemical Kinetics · Vol. 9, Issue 1, 2023 · pp. 20–27 Read article
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Nano based Phase Change Materials for Thermal Storage Applications: A Review
Abstract: Conventional thermal energy storage systems have low energy storage densities and are incapable of undergoing isothermal storage process. Phase Change Materials (PCMs) are gaining attention as potential materials for thermal energy storage from intermittent renewable energy sources. Latent heat storage materials (LHS) called PCMs can release or absorb heat energy when a change in physical state occurs. Although PCMs have high energy storage density, their poor thermal conductivity remains a …
Published in International Journal of Applied Nanotechnology · Vol. 7, Issue 2, 2021 · pp. 28–33 Read article
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Corrosion Protection of Rebar steel in Ocean Atmosphere
Abstract: Rebar is an important engineering metal. It is used in construction of housing, bridge and other infrastructures works. It is surround with concrete for strengthen building block components. The concentration of chloride ions in ocean atmosphere is higher so it produces hostile environment for rebar steel. The lots of porosities are available on the outer surface area of concrete so chloride ions enter inside by osmosis or diffusion process. It …
Published in International Journal of Energetic Materials · Vol. 8, Issue 1, 2022 · pp. 1–11 Read article
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Corrosion and Corrosion Protection of Carbon Steel
Abstract: Carbon steel is a very important metal for petroleum industries. Petroleum refineries are used bulk amount of carbon steel for purification of crude oil. Some amount of carbon dioxide and sulphur dioxide present in crude oil. Both gases are acidic in nature so they generate hostile medium for metal. These gases convert into carbonic and sulphuric acid and develop electrochemical cell on the surface of metal and aggravate corrosion reaction. …
Published in International Journal of Energetic Materials · Vol. 9, Issue 1, 2023 · pp. 28–35 Read article
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Effects of Tungstate and Nitrite Ions as Corrosion Inhibitor for Cr-10Zr-10W Alloy in 0.5 M NaCl Solution
Abstract: The effect of different concentrations of tungstate and nitrite ions as corrosion inhibitors on the corrosion behavior of the sputter-deposited ternary Cr–10Zr–10W alloy was studied in 0.5 M NaCl solution open to air at 25±1°C using corrosion tests and corrosion potential measurement. The use of both the tungstate and nitrite ions enhanced the corrosion resistance properties of the alloy in 0.5 M NaCl solution. It is found that the tungstate …
Published in International Journal of Metallurgy and Alloys · Vol. 5, Issue 1, 2019 · pp. 11–19 Read article
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Organic Compound 5-(4-methoxybenzyl)-N-phenyl-1,3,4-thiadiazol-2-amine and NiS filler used to Mitigation the Corrosion of Mild steel and in Marine Atmosphere
Abstract: The concentration of chloride ions is higher in marine atmosphere. The bulk amount of mild steel uses in sea weather for different works. This metal is very sensitive in chloride ions. It produces hostile environment for mild steel. Chloride ions develop corrosion cell on the surface of mild steel and it changes their external and internal morphology as well as physical, chemical and mechanical properties. Mild steel exhibits corrosion reaction …
Published in International Journal of Metallurgy and Alloys · Vol. 5, Issue 2, 2019 · pp. 56–64 Read article
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Study the Corrosive Effect of Greenhouse Gases on Metallic and Non-metallic Materials
Abstract: Carbon dioxide is a major corrosive pollutant for building materials. It enters inside materials by diffusion or osmosis process and in presence of moisture it produces H2CO3 which decrease the pH value and accelerates chemical and electrochemical reaction with building materials. The carbonation reaction produces deterioration inside and outside of building materials. It produces corrosion reaction with metallic bar and disbanding with concrete. CO2 reacts with Ca (OH)2 and Mg(OH)2 …
Published in International Journal of Metallurgy and Alloys · Vol. 7, Issue 2, 2021 · pp. 17–28 Read article
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Nanocoating and Electrospray Techniques Use to Mitigation Corrosion Sculptures
Abstract: The most sculptures of the world are created by the brass, bronze, iron, silver, gold and metalloid. They come in contact of corrosive pollutants to produce chemical, electrochemical and biochemical reactions and develop various form of corrosion like uniform corrosion, galvanic corrosion, pitting corrosion, stress corrosion and crevice corrosion. The corrosive gases CO2, NO2 and SO2 concentrations increase in atmosphere rapidly after industrialization. The major contributors of these gases are …
Published in International Journal of Metallurgy and Alloys · Vol. 8, Issue 2, 2022 · pp. 1–11 Read article
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Study of Mechanical Properties of Aluminum Nanocomposites using Auto Ignition Technique
Abstract: Al2O3 - high ZrO2 nanocomposite was synthesized by auto-ignition technique using metal nitrate and citric acid with a ratio of citrate: nitrate equal to 1:1.5. The precursor zirconium oxynitrite was derived from precipitation of zirconium oxycloride followed by dissolution of gel in nitric acid. The thermal decomposition behaviour of the gel was studied in order to study the decomposition behaviour and to determine the crystallization temperature. The effect of calcination …
Published in International Journal of Nanomaterials and Nanostructures · Vol. 3, Issue 2, 2017 · pp. 36–42 Read article
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A Detailed Lumped Model for Vinyl Acetate Emulsion Polymerization
Abstract: Abstract A mathematical model was developed to simulate emulsion polymerization of vinyl acetate monomer in isothermal, batch and semi-batch reactors. The recipe components included monomer (vinyl acetate), initiator (potassium persulfate), surfactant (sodium dodecyl sulfate) and water as the dispersion medium. The two important phenomena, particle nucleation and particle growth, were modeled in adequate detail. The mechanistic details included: particle formation via micellar nucleation; coupling of the radical concentration in the …
Published in International Journal of Polymer Science and Engineering · Vol. 5, Issue 1, 2019 · pp. 1–12 Read article
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A Model to Study the Effect of Homogeneous Nucleation and Emulsifier Amounts on Methyl Methacrylate Emulsion Polymerization in a Seeded Semi-batch Reactor
Abstract: ABSTRACTAn extensive model is developed for methyl methacrylate emulsion polymerization. The assumption of monodispersed particle size distribution is used in developing the model. It is found that inclusion of homogeneous nucleation in the model leads to under prediction of variation of conversion with time. The effects of three different emulsifier amounts on the variation of conversion with time at 50°C isothermal reactor operation, keeping all the other ingredients constant are …
Published in International Journal of Polymer Science and Engineering · Vol. 5, Issue 2, 2019 · pp. 9–17 Read article
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Predictive Model on Constant Pressure Drop Variable: Area Fluid Flow System in a Pipe
Abstract: The effect of density, pressure drop, and orifice area was examined in this research. The basic equation developed to represent steady-state fluid flow is the Bernoulli equation which assumes that the total mechanical energy is conserved for steady incompressible, in viscid, isotherm flow with no heat transfer or work done. These restrictive conditions can actually be representative of many physical systems. The Bernoulli’s principle was applied in explaining the design …
Published in International Journal of Mechanics and Design · Vol. 4, Issue 1, 2018 · pp. 23–34 Read article