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By: U. M. Adam, S. Abdulsalam, and U. D. Hamza
Department of Chemical Engineering, Abubakar Tafawa Balewa University, PMB-0248, Bauchi, Nigeria.
Department of Chemical Engineering, Federal University, Wukari, Taraba, Nigeria.
Large amounts of produced water are produced in tandem with the production of crude oil. Both dissolved and dispersed oil are present in produced water, which can contaminate the environment and pose health risks to people. In this study, the oil component, cadmium, and lead ions were extracted from the generated water using sesame residues and agricultural wastes. The sesame residues were dried, size-reduced, and ground. Standard techniques were used to produce the biosorbent and remove the lead, cadmium, and oil ions in a batch operation. After 30 minutes of equilibrium time and an initial oil concentration of 435.5 mg/l, biosorption experiments using the sesame pod and stalk demonstrated that both residues can be used to remove crude oil, cadmium, and lead ions from produced water. The removal rates for the sesame pod and stalk were nearly 96.7% and 97.2%, respectively, at an equivalent dosage of 1.0 g per liter of produced water. The findings of testing a number of kinetic models revealed that sesame stalk biosorbent followed a second-order kinetic model, while sesame pod biosorbent followed a pseudo-first-order kinetic model. Conversely, investigations using equilibrium isotherms showed that sesame stalks followed the Temkin isotherm whereas sesame pods followed.
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