Design and Analysis of Metal-Organic Frameworks for Gas Adsorption and Storage

Volume: 10 | Issue: 1 | Year 2024 | Subscription
International Journal of Metallurgy and Alloys
Received Date: 08/12/2024
Acceptance Date: 09/15/2024
Published On: 2024-11-20
First Page: 25
Last Page: 30

Journal Menu

By: Neha Sahu and Rizwan Arif

1Research Scholar, Department of Chemistry, School of Basic & Applied Sciences, Lingaya’s Vidyapeeth, Faridabad, Haryana, India.
2Assistant Professor, Department of Chemistry, School of Basic & Applied Sciences, Lingaya’s Vidyapeeth, Faridabad, Haryana, India.

Abstract

Metal-Organic Frameworks (MOFs) represent a class of highly porous materials formed by the coordination of metal ions with organic linkers, exhibiting exceptional potential for gas storage applications due to their high surface area, tunable pore sizes, and structural versatility. The synthesis and characterization of MOFs intended for the effective storage of gases like carbon dioxide, methane, and hydrogen are the main topics of this work. Solvothermal Hectic strategies, including solvothermal, hydrothermal, and microwave-assisted methods, were employed to optimize the formation of MOFs with desired properties. The synthesized MOFs were characterized using a suite of techniques including X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and nitrogen adsorption-desorption isotherms to evaluate their crystallinity, functional groups, morphology, and surface area, respectively. The gas adsorption capacities were assessed using volumetric and gravimetric methods under varying conditions of pressure and temperature. The results demonstrated that the MOFs exhibited significant adsorption capacities, highlighting their potential as materials for gas storage in applications ranging from clean energy storage to carbon capture and sequestration.

Loading

Citation:

How to cite this article: Neha Sahu and Rizwan Arif, Design and Analysis of Metal-Organic Frameworks for Gas Adsorption and Storage. International Journal of Metallurgy and Alloys. 2024; 10(1): 25-30p.

How to cite this URL: Neha Sahu and Rizwan Arif, Design and Analysis of Metal-Organic Frameworks for Gas Adsorption and Storage. International Journal of Metallurgy and Alloys. 2024; 10(1): 25-30p. Available from:https://journalspub.com/publication/ijma/article=12169

Refrences:

  1. Babu S, Manoharan S, Ottappilakkil H, Perumal E. Role of oxidative stress-mediated cell death and signaling pathways in experimental fluorosis. Chem Biol Interact. 2022 Sep 25;365:110106.
  2. Cai X, Xie Z, Li D, Kassymova M, Zang SQ, Jiang HL. Nano-sized metal-organic frameworks: Synthesis and applications. Coord Chem Rev. 2020 Aug 15;417:213366.
  3. Chen H, You Z, Wang X, Qiu Q, Ying Y, Wang Y. An artificial olfactory sensor based on flexible metal–organic frameworks for sensing VOCs. Chem Eng J. 2022 Oct 15;446:137098.
  4. Chen J, Wang G, Su X. Fabrication of red-emissive ZIF-8@ QDs nanoprobe with improved fluorescence based on assembly strategy for enhanced biosensing. Sens Actuators B Chem 2022 Oct 1;368:132188.
  5. Cheng W, Tang X, Zhang Y, Wu D, Yang W. Applications of metal-organic framework (MOF)-based sensors for food safety: Enhancing mechanisms and recent advances. Trends Food Sci Technol. 2021 Jun 1;112:268-82.
  6. Davey AK, Gao X, Xia Y, Li Z, Dods MN, Delacruz S, Pan A, Swamy S, Gardner D, Carraro C, Maboudian R. Amine-functionalized metal-organic framework ZIF-8 toward colorimetric CO2 sensing in indoor air environment. Sens Actuators B Chem. 2021 Oct 1;344:130313.
  7. Ding M, Liu W, Gref R. Nanoscale MOFs: From synthesis to drug delivery and theranostics applications. Adv Drug Deliv Rev. 2022 Nov 1;190:114496.
  8. Duan S, Dou B, Lin X, Zhao S, Emori W, Pan J, Hu H, Xiao H. Influence of active nanofiller ZIF-8 metal-organic framework (MOF) by microemulsion method on anticorrosion of epoxy coatings. Colloids Surf A Physicochem Eng Asp. 2021 Sep 5;624:126836.
  9. Khan MF, Marwat MA, Shah SS, Karim MR, Aziz MA, Din ZU, Ali S, Adam KM. Novel MoS2-sputtered NiCoMg MOFs for high-performance hybrid supercapacitor applications. Sep Purif Technol. 2023 Apr 1;310:123101.
  10. Feng Y, Wang Y, Ying Y. Structural design of metal–organic frameworks with tunable colorimetric responses for visual sensing applications. Coord Chem Rev. 2021 Nov 1;446:214102.
  11. Geng P, Yu N, Macharia DK, Meng R, Qiu P, Tao C, Li M, Zhang H, Chen Z, Lian W. MOF-derived CuS@ Cu-MOF nanocomposites for synergistic photothermal-chemodynamic-chemo therapy. Chem Eng J. 2022 Aug 1;441:135964.
  12. Gu C, Bai L, Pu L, Gai P, Li F. Highly sensitive and stable self-powered biosensing for exosomes based on dual metal-organic frameworks nanocarriers. Biosens Bioelectron.. 2021 Mar 15;176:112907.
  13. Gu C, Liu J, Hu J, Wu D. Highly efficient separations of C2H2 from C2H2/CO and C2H2/H2 in metal–organic frameworks with ZnF2 chelation: A molecular simulation study. Fuel. 2020 Jul 1;271:117598.
  14. Gupta NK, Kim S, Bae J, Kim KS. Fabrication of Cu (BDC) 0.5 (BDC-NH2) 0.5 metal-organic framework for superior H2S removal at room temperature. Chem Eng J. 2021 May 1;411:128536.
  15. Hakimifar A, Morsali A. High-sensitivity detection of nitroaromatic compounds (NACs) by the pillared-layer metal-organic framework synthesized via ultrasonic method. Ultrason Sonochem. 2019 Apr 1;52:62-8.
  16. Hao F, Yan XP. Nano-sized zeolite-like metal-organic frameworks induced hematological effects on red blood cell. J Hazard Mater. 2022 Feb 15;424:127353.
  17. Hao F, Yan XP. Nano-sized zeolite-like metal-organic frameworks induced hematological effects on red blood cell. Sci Total Environ. 2022 Feb 15;424:127353.
  18. Hao F, Yan ZY, Yan XP. Size-and shape-dependent cytotoxicity of nano-sized Zr-based porphyrinic metal-organic frameworks to macrophages. SciTtl Environ. 2022 Aug 10;833:155309.